Here are the eight teams that make it to the quarterfinals. Only last year's gold medalists, the Williams sisters survive the second round. This means that three new doubles pairs will get to the medal round this year.
| QUARTERFINALS |
| Serena Williams / Venus Williams (USA) (1) |
| Victoria Azarenka / Aliaksandra Sasnovich (BLR) |
| Simona Halep / Irina Camelia Begu (ROU) (6) |
| Petra Kvitova / Karolina Pliskova (CZE) (4) |
| Garbine Muguruza / Carla Suarez Navarro (ESP) (2) |
| Jelena Jankovic / Ana Ivanovic (SRB) |
| Sloane Stephens / Madison Keys (USA) (8) |
| Lucie Safarova / Barbora Strycova (CZE) |
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